International
Tables for Crystallography Volume C Mathematical, physical and chemical tables Edited by E. Prince © International Union of Crystallography 2006 |
International Tables for Crystallography (2006). Vol. C. ch. 2.6, p. 108
Section 2.6.2.4. Long wavelengths
R. Mayb
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An important aspect of neutron scattering is the ease of using long wavelengths: Long-wavelength X-rays are produced efficiently only by synchrotrons, and therefore their cost is similar to that of neutrons. Unlike neutrons, however, they suffer from their strong interaction with matter. This disadvantage, which is acceptable with the commonly used Cu Kα radiation, is in most cases prohibitive for wavelengths of the order of 1 nm.
Very low Q values are more easily obtained with long wavelengths than with very small angles, as is necessary with X-rays, since the same Q value can be observed further away from the direct beam. Objects of linear dimensions of several 100 nm, e.g. opals, where spherical particles of amorphous silica form a close-packed lattice with cell dimensions of up to several hundreds of nm, can still be investigated easily with neutrons. X-ray double-crystal diffractometers (Bonse & Hart, 1966), which may also reach very low Q, are subject to transmission problems, and neutron DCD's again perform better.
References
Bonse, U. & Hart, M. (1966). Small-angle X-ray scattering by spherical particles of polystyrene and polyvinyltoluene. Z. Phys. 189, 151–162.Google Scholar