International
Tables for
Crystallography
Volume F
Crystallography of biological macromolecules
Edited by M. G. Rossmann and E. Arnold

International Tables for Crystallography (2006). Vol. F. ch. 23.3, p. 592   | 1 | 2 |

Figure 23.3.2.4 

R. E. Dickersona*

a Molecular Biology Institute, University of California, Los Angeles, Los Angeles, CA 90095–1570, USA
Correspondence e-mail: red@mbi.ucla.edu

[Figure 23.3.2.4]
Figure 23.3.2.4

The three most common furanose ring geometries. The planar form of the five-membered ribose or deoxyribose ring is unstable because of steric hindrance from side groups; one of the five atoms prefers to pucker out-of-plane on one side of the ring or the other. Puckering toward the same side of the ring as the C5′ atom is termed endo, and puckering toward the opposite `outside' surface is termed exo. The main-chain torsion angle δ is related to sugar ring conformation because of the motion undergone by the C3′—O3′ bond during changes in puckering.