International
Tables for
Crystallography
Volume A
Space-group symmetry
Edited by Th. Hahn

International Tables for Crystallography (2006). Vol. A. ch. 2.2, p. 23

Section 2.2.6.6. Rhombohedral (trigonal R) space groups

Th. Hahna* and A. Looijenga-Vosb

a Institut für Kristallographie, Rheinisch-Westfälische Technische Hochschule, Aachen, Germany, and bLaboratorium voor Chemische Fysica, Rijksuniversiteit Groningen, The Netherlands
Correspondence e-mail:  hahn@xtl.rwth-aachen.de

2.2.6.6. Rhombohedral (trigonal R) space groups

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The seven rhombohedral R space groups are treated in two versions, the first based on `hexagonal axes' (obverse setting), the second on `rhombohedral axes' (cf. Sections 2.1.3[link] and 2.2.2[link]). The pairs of diagrams are similar to those in IT (1952)[link]; the left or top one displays the symmetry elements, the right or bottom one the general position. This is illustrated in Fig. 2.2.6.9[link], which gives the axes a and b of the triple hexagonal cell and the projections of the axes of the primitive rhombohedral cell, labelled [a_{p},\ b_{p}] and [c_{p}]. For convenience, all `heights' in the space-group diagrams are fractions of the hexagonal c axis. For `hexagonal axes', the projection direction is [001], for `rhombohedral axes' it is [111]. In the general-position diagrams, the circles drawn in heavier lines represent atoms that lie within the primitive rhombohedral cell (provided the symbol `−' is read as [1 - z] rather than as [- z]).

[Figure 2.2.6.9]

Figure 2.2.6.9| top | pdf |

Rhombohedral R space groups. Obverse triple hexagonal cell with `hexagonal axes' a, b and primitive rhombohedral cell with projections of `rhombohedral axes' [a_{p}, b_{p}, c_{p}]. Note: In the actual space-group diagrams only the upper edges (full lines), not the lower edges (dashed lines) of the primitive rhombohedral cell are shown ([\hbox{\sf G}] = general-position diagram).

The pairs of drawings for the hexagonal and the rhombohedral descriptions of a space group are the same. In the rhombohedral descriptions of space groups Nos. 166 and 167, [R\bar{3}m] and [R\bar{3}c], the diagrams are omitted for reasons of space, and the reader is referred to the drawings in the hexagonal descriptions.

References

First citation International Tables for X-ray Crystallography (1952). Vol. I, edited by N. F. M. Henry & K. Lonsdale. Birmingham: Kynoch Press. [Revised editions: 1965, 1969 and 1977. Abbreviated as IT (1952).]Google Scholar








































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