International
Tables for
Crystallography
Volume A
Space-group symmetry
Edited by Th. Hahn

International Tables for Crystallography (2006). Vol. A. ch. 4.3, p. 75

Section 4.3.6.2. Relations between symmetry elements

E. F. Bertauta

a Laboratoire de Cristallographie, CNRS, Grenoble, France

4.3.6.2. Relations between symmetry elements

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Conventionally, the representative directions of the primary, secondary and tertiary symmetry elements are chosen as [001], [111], and [[1\bar{1}0]] (cf. Table 2.2.4.1[link] for the equivalent directions). As in tetragonal and hexagonal space groups, tertiary symmetry elements are not independent. In classes 432, [\bar{4}3m] and [m\bar{3}m], there are product rules [4 \times 3 = (2){\hbox{;}}\quad \bar{4} \times 3 = (m) = 4 \times \bar{3},] where the tertiary symmetry element is in parentheses; analogous rules hold for the space groups belonging to these classes. When the symmetry directions of the primary and secondary symmetry elements are chosen along [001] and [111], respectively, the tertiary symmetry direction is [011], according to the product rule. In order to have the tertiary symmetry direction along [[1\bar{1}0]], one has to choose the somewhat awkward primary and secondary symmetry directions [010] and [[\bar{1}1\bar{1}]].

Examples

  • (1) In [P\bar{4}3n] (218), with the choice of the 3 axis along [[\bar{1}1\bar{1}]] and of the [\bar{4}] axis parallel to [010], one finds [\bar{4} \times 3 = n], the n glide plane being in x, x, z, as shown in the space-group diagram.

  • (2) In [F\bar{4}3c] (219), one has the same product rule as above; the centring translation [t({1 \over 2},{1 \over 2},0)], however, associates with the n glide plane a c glide plane, also located in x, x, z (cf. Table 4.1.2.3[link] ). In the space-group diagram and symbol, c was preferred to n.








































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