International
Tables for Crystallography Volume B Reciprocal space Edited by U. Shmueli © International Union of Crystallography 2006 |
International Tables for Crystallography (2006). Vol. B. ch. 2.1, pp. 192-193
Section 2.1.4.1. Characteristic functions^{a}School of Chemistry, Tel Aviv University, Tel Aviv 69 978, Israel, and ^{b}St John's College, Cambridge, England |
The average value of is very important in probability theory; it is called the characteristic function of the distribution and is denoted by or, when no confusion can arise, by . It exists for all legitimate distributions, whether discrete or continuous. In the continuous case it is given by and is thus the Fourier transform of . In many cases it can be obtained from known integrals. For example, for the Cauchy distribution, and for the normal distribution, Since the characteristic function is the Fourier transform of the distribution function, the converse is true, and if the characteristic function is known the probability distribution function can be obtained by the use of Fourier inversion theorem, An alternative approach to the derivation of the distribution from a known characteristic function will be discussed below.
The most important property of characteristic functions in crystallography is the following: if x and y are independent random variables with characteristic functions and , the characteristic function of their sum is the product Obviously this can be extended to any number of independent random variables.
When the moments exist, the characteristic function can be expanded in a power series in which the kth term is . If the power series is substituted in equation (2.1.4.1), one obtains The moments are written with primes in order to indicate that equation (2.1.4.10) is valid for moments about an arbitrary origin as well as for moments about the mean. If the random variable is transformed by a change of origin and scale, say the characteristic function for y becomes