International
Tables for Crystallography Volume B Reciprocal Space Edited by U. Shmueli © International Union of Crystallography 2006 |
International Tables for Crystallography (2006). Vol. B. ch. 5.3, p. 558
Section 5.3.2.5. Translating X-ray dynamical theory into the neutron case
aLaboratoire Louis Néel du CNRS, BP 166, F-38042 Grenoble CEDEX 9, France, and bEuropean Synchrotron Radiation Facility, BP 220, F-38043 Grenoble, France |
As shown in Chapter 5.1 , the basic equations of dynamical theory, viz Maxwell's equations for the X-ray case and the time-independent Schrödinger equation in the neutron case, have exactly the same form when the effect of the neutron spin can be neglected, i.e. in situations that do not involve magnetism and when no externally applied potential is taken into account. The translation scheme for the scattering factors and structure factors is described above. The one formal difference is that the wavefunction is scalar in the neutron case, hence there is no equivalent to the parallel and perpendicular polarizations of the X-ray situation: C in equation (5.1.2.20 ) of Chapter 5.1 should therefore be set to 1.
The physics of neutron diffraction by perfect crystals is therefore expected to be very similar to that of X-ray diffraction, with the existence of wavefields, Pendellösung effects, anomalous transmission, intrinsic rocking-curve shapes and reflectivity versus thickness behaviour in direct correspondence. All experimental tests of these predictions confirm this view (Section 5.3.6).
Basic discussions of dynamical neutron scattering are given by Stassis & Oberteuffer (1974), Sears (1978), Rauch & Petrascheck (1978), and Squires (1978).
References
Rauch, H. & Petrascheck, D. (1978). Dynamical neutron diffraction and its application. In Neutron diffraction, edited by H. Dachs, Topics in current physics, Vol. 6 pp. 305–351. Berlin: Springer.Google ScholarSears, V. F. (1978). Dynamical theory of neutron diffraction. Can. J. Phys. 56, 1261–1288.Google Scholar
Squires, G. L. (1978). Introduction to the theory of thermal neutron scattering. Cambridge University Press.Google Scholar
Stassis, C. & Oberteuffer, J. A. (1974). Neutron diffraction by perfect crystals. Phys. Rev. B, 10, 5192–5202.Google Scholar