International
Tables for
Crystallography
Volume C
Mathematical, physical and chemical tables
Edited by E. Prince

© International Union of Crystallography 2006
International Tables for Crystallography (2006). Vol. C. ch. 9.4, pp. 779-780

Table 9.4.1.1 

G. Bergerhoffa and K. Brandenburga

a Institut für Anorganische Chemie der Universität Bonn, Gerhard-Domagkstrasse 1, D-53121 Bonn, Germany

Table 9.4.1.1 | top | pdf |
Atomic distances between halogens and main-group elements in their preferred oxidation states

Atom pair N Mean s.u. d 1 Smallest 5% First quartile Median Third quartile d 2
Li+—F− 108 193.0 14.2 150.0 166.4 184.6 195.0 202.7 250.0
Na+—F− 265 230.8 19.7 0.0 211.5 222.7 227.8 236.7 500.0
K+—F− 354 269.3 19.5 180.0 241.8 258.5 267.0 282.3 340.0
Rb+—F− 158 294.2 17.5 250.0 268.6 280.8 292.9 309.2 350.0
Cs+—F− 230 311.3 13.6 260.0 290.1 303.0 312.8 319.6 360.0
Li+—Cl− 30 246.1 11.1 210.0 223.0 240.3 247.0 255.0 300.0
Na+—Cl− 100 282.7 11.5 250.0 267.5 273.4 280.5 290.8 330.0
K+—Cl− 191 318.8 16.1 270.0 296.4 308.7 316.8 328.4 370.0
Rb+—Cl− 135 336.4 14.8 290.0 319.5 325.1 333.2 348.9 390.0
Cs+—Cl− 216 356.9 17.9 290.0 333.6 344.8 357.7 367.7 420.0
Li+—Br− 9 282.3 27.7 0.0 246.9 266.5 275.0 287.5 500.0
Na+—Br− 15 303.8 18.5 270.0 281.5 294.8 298.2 312.5 360.0
K+—Br− 72 331.8 26.4 0.0 289.2 314.0 332.0 342.7 500.0
Rb+—Br− 48 349.2 16.1 300.0 325.4 337.0 348.7 360.5 400.0
Cs+—Br− 64 372.2 15.3 350.0 352.4 360.0 368.3 385.0 430.0
Li+—I− 7 307.9 26.0 270.0 274.7 283.5 303.0 326.5 370.0
Na+—I− 7 342.1 24.5 0.0 320.7 322.8 325.0 372.2 500.0
K+—I− 24 363.6 29.2 0.0 334.4 344.0 364.0 374.0 500.0
Rb+—I− 29 372.0 16.3 320.0 340.9 362.8 373.0 381.2 430.0
Cs+—I− 63 393.4 13.8 350.0 374.8 381.9 391.7 404.8 450.0
Be2+—F− 78 150.6 6.3 120.0 140.6 148.2 152.2 153.9 200.0
Mg2+—F− 96 198.8 9.2 150.0 188.2 195.1 200.7 203.3 250.0
Ca2+—F− 127 230.9 16.9 0.0 216.2 223.8 228.7 236.2 500.0
Sr2+—F− 35 246.5 9.6 0.0 227.8 241.5 246.2 250.2 500.0
Ba2+—F− 94 266.6 9.3 0.0 256.7 259.9 264.6 269.3 500.0
Be2+—Cl− 2 200.0 1.4 0.0 198.2 199.0 200.0 201.0 500.0
Mg2+—Cl− 16 250.9 11.9 210.0 229.6 246.7 249.0 258.0 300.0
Ca2+—Cl− 55 286.2 15.1 260.0 271.8 275.1 280.8 293.2 350.0
Sr2+—Cl− 42 302.4 6.7 0.0 294.2 301.6 303.0 304.8 500.0
Ba2+—Cl− 64 316.3 12.2 270.0 298.8 308.7 314.8 324.0 370.0
Ca2+—Br− 10 300.6 18.9 250.0 259.0 290.5 308.0 311.0 350.0
Sr2+—Br− 30 305.4 15.5 0.0 279.0 291.0 311.0 315.0 500.0
Ba2+—Br− 17 331.9 13.2 0.0 307.7 320.5 337.0 340.8 500.0
Ca2+—I− 4 324.5 11.8 300.0 312.4 314.0 322.0 324.0 360.0
Sr2+—I− 20 305.7 20.6 250.0 278.0 284.7 312.7 322.0 350.0
Ba2+—I− 8 348.2 9.7 0.0 336.4 338.0 346.0 357.0 500.0
B3+—F− 39 136.6 7.1 110.0 125.9 133.8 136.8 139.1 180.0
Al3+—F− 121 180.6 7.5 150.0 170.1 176.6 179.3 184.6 230.0
Ga3+—F− 17 191.2 6.0 0.0 183.7 186.8 189.7 193.9 500.0
In3+—F− 24 204.0 9.1 0.0 192.4 202.0 204.6 206.7 500.0
Tl3+—F− 14 203.0 6.7 0.0 189.4 199.0 203.3 208.5 500.0
B3+—Cl− 8 175.8 16.9 140.0 142.8 173.0 176.0 178.0 220.0
Al3+—Cl− 50 211.1 7.2 190.0 204.3 209.8 211.1 212.4 270.0
Ga3+—Cl− 12 212.8 4.4 0.0 204.6 211.0 213.3 216.0 500.0
In3+—Cl− 20 248.7 10.7 220.0 238.0 241.2 246.0 253.0 300.0
Tl3+—Cl− 19 248.2 6.9 200.0 233.9 243.5 249.0 253.2 300.0
B3+—Br− 3 197.7 13.6 150.0 186.3 187.5 193.0 212.5 250.0
Al3+—Br− 4 226.5 5.7 0.0 222.2 223.0 224.0 226.0 500.0
Ga3+—Br− 4 230.0 3.5 0.0 224.4 226.0 231.0 232.0 500.0
In3+—Br− 11 262.6 11.9 0.0 248.6 250.8 261.0 274.2 500.0
Tl3+—Br− 13 253.3 6.0 0.0 245.3 250.2 253.0 255.8 500.0
B3+—I− 2 240.0 41.0 200.0 210.2 211.0 212.0 269.0 300.0
Al3+—I− 3 248.3 2.3 220.0 246.1 246.8 247.5 250.5 280.0
Ga3+—I− 2 253.0 0.0 0.0 252.1 252.5 253.0 253.5 500.0
In3+—I− 7 275.9 10.3 250.0 264.4 265.8 275.0 280.5 320.0
Ge4+—F− 20 176.7 3.9 150.0 168.0 176.0 177.1 178.4 210.0
Sn4+—F− 24 195.8 6.4 0.0 184.4 194.6 196.3 198.0 500.0
Pb4+—F− 9 209.7 7.2 0.0 196.9 206.5 210.5 212.8 500.0
C4+—Cl− 6 163.0 21.8 120.0 120.6 157.0 174.0 175.5 200.0
Sn4+—Cl− 46 238.7 5.7 0.0 230.1 235.0 240.4 242.7 500.0
Pb4+—Cl− 9 249.0 2.0 0.0 244.9 248.4 249.0 249.6 500.0
Sn4+—Br− 5 251.0 9.7 0.0 236.5 244.5 255.0 258.8 500.0
Ge4+—I− 3 254.3 4.6 0.0 248.3 249.5 256.5 257.2 500.0
Sn4+—I− 10 263.4 20.9 0.0 209.0 263.5 265.0 269.0 500.0
Pb4+—I− 2 310.0 1.4 0.0 308.2 309.0 310.0 311.0 500.0
P5+—F− 40 155.6 6.4 130.0 144.0 151.3 156.8 159.3 200.0
As5+—F− 89 164.6 6.7 130.0 155.4 160.9 165.5 168.4 200.0
Sb5+—F− 81 182.6 6.5 150.0 174.1 179.2 182.7 184.7 230.0
Bi5+—F− 9 192.1 11.3 0.0 178.4 188.2 189.7 195.5 500.0
P5+—Cl− 52 193.2 3.6 170.0 187.2 190.6 193.3 195.4 210.0
Sb5+—Cl− 66 233.1 6.6 200.0 220.6 229.8 233.8 236.4 270.0
P5+—Br− 12 211.2 5.1 0.0 201.2 208.0 213.0 214.7 500.0
Sb5+—Br− 6 254.0 2.1 250.0 250.6 252.5 254.0 255.5 270.0
S6+—F− 25 151.1 4.2 140.0 141.2 150.1 152.1 153.7 160.0
Te6+—F− 9 176.1 6.9 0.0 160.9 174.5 179.0 180.5 500.0
S6+—Cl− 10 197.6 5.7 170.0 185.0 195.5 197.3 201.0 220.0
I7+—F− 6 179.7 4.7 0.0 170.6 179.0 180.7 181.7 500.0