International
Tables for Crystallography Volume F Crystallography of biological macromolecules Edited by M. G. Rossmann and E. Arnold © International Union of Crystallography 2006 |
International Tables for Crystallography (2006). Vol. F. ch. 23.3, p. 592
Figure 23.3.2.4
a
Molecular Biology Institute, University of California, Los Angeles, Los Angeles, CA 90095–1570, USA |
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Figure 23.3.2.4
The three most common furanose ring geometries. The planar form of the five-membered ribose or deoxyribose ring is unstable because of steric hindrance from side groups; one of the five atoms prefers to pucker out-of-plane on one side of the ring or the other. Puckering toward the same side of the ring as the C5′ atom is termed endo, and puckering toward the opposite `outside' surface is termed exo. The main-chain torsion angle δ is related to sugar ring conformation because of the motion undergone by the C3′—O3′ bond during changes in puckering. |