International
Tables for Crystallography Volume F Crystallography of biological macromolecules Edited by M. G. Rossmann and E. Arnold © International Union of Crystallography 2006 |
International Tables for Crystallography (2006). Vol. F. ch. 23.3, p. 593
Figure 23.3.2.5
a
Molecular Biology Institute, University of California, Los Angeles, Los Angeles, CA 90095–1570, USA |
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Figure 23.3.2.5
Potential plot of all furanose ring conformations. Energies are in kcal mol −1. The distance from the central point gives the maximum displacement of the out-of-plane atom from the plane of the other four. The circle is a constant-displacement trajectory chosen to pass through the potential minima on the right three-quarters of the plot. C2′-endo and C3′-endo are especially favoured, whereas O1′-exo on the left is highly disfavoured. The path from C2′-endo through C1′-exo, O1′-endo and C4′-exo to C3′-endo is a low-energy path, and many examples all along this path are known in B-DNA helices. Reprinted with permission from Levitt & Warshel (1978 |