International
Tables for
Crystallography
Volume C
Mathematical, physical and chemical tables
Edited by E. Prince

© International Union of Crystallography 2006
International Tables for Crystallography (2006). Vol. C. ch. 9.4, pp. 781-784

Table 9.4.1.3 

G. Bergerhoffa and K. Brandenburga

a Institut für Anorganische Chemie der Universität Bonn, Gerhard-Domagkstrasse 1, D-53121 Bonn, Germany

Table 9.4.1.3 | top | pdf |
Atomic distances between halogens and transition metals

Atom pair N Mean s.u. d 1 Smallest 5% First quartile Median Third quartile d 2
Sc3+—F− 17 206.8 13.5 0.0 193.7 200.2 204.5 207.4 500.0
Ti3+—F− 10 191.8 4.4 0.0 186.5 188.5 191.0 193.5 500.0
Ti4+—F− 37 190.1 11.2 0.0 177.7 184.9 188.8 191.4 500.0
V4+—F− 14 183.3 11.1 0.0 160.7 179.0 188.0 191.0 500.0
V5+—F− 13 183.6 9.1 0.0 165.3 178.5 186.3 189.5 500.0
Cr2+—F− 10 201.2 5.2 0.0 195.0 197.5 199.3 207.0 500.0
Cr3+—F− 68 192.6 12.1 0.0 184.1 187.5 190.9 195.1 500.0
Cr4+—F− 13 183.0 7.5 0.0 167.3 180.5 185.5 188.5 500.0
Cr6+—F− 3 163.0 5.3 140.0 156.3 157.5 165.0 166.5 200.0
Fe2+—F− 40 204.4 8.7 160.0 188.0 199.2 204.3 208.0 250.0
Fe3+—F− 103 189.7 6.5 150.0 180.8 187.4 190.7 192.7 240.0
Co2+—F− 28 200.9 8.0 180.0 193.4 196.7 200.0 203.2 250.0
Co3+—F− 12 189.2 2.6 160.0 183.2 188.0 189.5 191.0 220.0
Ni2+—F− 66 196.5 6.2 170.0 188.9 193.0 195.9 199.4 250.0
Ni3+—F− 8 186.0 3.2 0.0 178.8 185.0 186.7 188.0 500.0
Ni4+—F− 7 176.7 4.1 0.0 170.4 171.8 178.3 179.5 500.0
Cu2+—F− 82 195.6 12.8 160.0 184.6 188.3 191.6 197.0 250.0
Cu3+—F− 7 185.9 7.8 0.0 172.7 182.5 183.7 194.2 500.0
Zn2+—F− 48 197.2 11.2 150.0 178.8 194.0 198.4 202.7 250.0
Sc3+—Cl− 9 255.7 6.9 0.0 240.9 254.2 255.7 257.8 500.0
Ti3+—Cl− 6 244.0 6.3 0.0 232.6 241.0 246.0 247.5 500.0
Ti4+—Cl− 16 225.0 17.0 170.0 181.6 219.0 224.0 234.7 270.0
V2+—Cl− 8 250.0 2.8 0.0 246.3 247.3 250.0 252.7 500.0
V3+—Cl− 10 235.6 4.6 0.0 227.0 233.0 236.0 237.7 500.0
V4+—Cl− 4 227.5 7.7 0.0 216.4 218.0 228.0 232.0 500.0
V5+—Cl− 5 221.0 5.8 200.0 212.5 218.5 221.0 223.5 250.0
Cr2+—Cl− 30 246.7 15.2 220.0 236.2 239.0 241.2 247.0 320.0
Cr3+—Cl− 17 231.6 4.8 200.0 217.7 229.5 232.5 233.9 270.0
Cr6+—Cl− 3 218.3 1.2 200.0 216.3 217.5 218.5 219.2 250.0
Fe2+—Cl− 29 244.9 10.2 200.0 222.4 243.2 247.8 251.2 280.0
Fe3+—Cl− 39 227.1 9.8 200.0 216.2 217.9 226.5 235.2 280.0
Co2+—Cl− 39 237.6 12.4 200.0 220.5 225.2 244.1 247.3 280.0
Co3+—Cl− 10 228.4 30.5 150.0 167.0 225.0 228.0 231.0 310.0
Ni2+—Cl− 12 238.3 6.1 200.0 221.2 237.0 240.0 242.0 280.0
Cu+—Cl− 38 245.5 25.5 210.0 217.3 229.0 235.2 270.5 320.0
Cu2+—Cl− 51 228.1 5.1 200.0 217.1 225.9 228.7 230.4 240.0
Zn2+—Cl− 54 227.5 9.1 200.0 218.4 222.7 225.0 230.1 280.0
Ti4+—Br− 3 249.0 18.0 0.0 230.3 231.5 249.0 266.5 500.0
V2+—Br− 5 259.8 6.3 0.0 248.5 260.2 261.5 263.5 500.0
V3+—Br− 5 250.6 2.6 0.0 246.5 248.5 251.0 252.8 500.0
Cr2+—Br− 7 247.3 8.0 0.0 238.7 240.8 243.0 255.2 500.0
Cr3+—Br− 7 244.1 4.7 210.0 238.7 240.8 243.0 246.5 290.0
Mn2+—Br− 12 261.2 11.2 220.0 235.2 259.0 265.0 268.0 320.0
Fe2+—Br− 7 247.9 10.9 220.0 232.7 235.5 249.0 258.5 290.0
Fe3+—Br− 4 239.0 13.4 220.0 230.4 232.0 233.0 234.0 290.0
Co2+—Br− 8 253.0 7.9 0.0 238.8 248.7 250.0 260.7 500.0
Ni2+—Br− 3 257.7 7.0 0.0 250.3 251.5 257.0 264.5 500.0
Cu+—Br− 22 260.8 20.1 210.0 236.2 246.5 253.0 277.5 310.0
Cu2+—Br− 18 260.3 23.3 210.0 231.8 244.5 251.0 287.5 310.0
Zn2+—Br− 17 235.0 14.5 200.0 203.7 234.5 236.9 237.9 300.0
V2+—I− 4 287.0 7.3 0.0 278.4 280.0 284.0 292.0 500.0
Cr2+—I− 20 261.2 31.6 0.0 190.0 242.0 275.0 278.5 500.0
Mn2+—I− 10 287.2 6.4 0.0 275.0 281.0 290.0 291.7 500.0
Fe2+—I− 3 268.3 15.0 240.0 250.3 251.5 276.5 277.2 300.0
Ni2+—I− 4 295.5 11.0 250.0 278.4 280.0 300.7 301.3 310.0
Cu+—I− 36 268.7 16.9 0.0 248.8 258.0 264.4 272.0 500.0
Zn2+—I− 5 264.6 17.2 240.0 252.5 256.2 257.5 261.5 310.0
Y3+—F− 34 226.7 18.9 0.0 199.4 217.0 224.7 235.0 500.0
Zr4+—F− 66 203.1 10.1 0.0 191.5 199.0 201.5 205.4 500.0
Nb3+—F− 6 195.0 2.2 0.0 190.6 194.3 195.3 196.5 500.0
Nb4+—F− 5 201.8 3.6 0.0 196.5 198.5 203.0 204.8 500.0
Nb5+—F− 52 191.0 12.7 150.0 159.2 184.5 192.0 199.5 240.0
Mo3+—F− 11 204.1 6.3 0.0 195.1 202.3 203.4 204.8 500.0
Mo5+—F− 8 185.5 10.1 160.0 172.4 174.0 185.0 186.0 230.0
Mo6+—F− 17 190.1 12.5 150.0 169.7 180.5 190.5 193.8 250.0
Ru5+—F− 7 182.1 9.0 0.0 166.7 176.8 183.0 190.2 500.0
Rh3+—F− 14 196.3 4.8 170.0 181.4 195.5 198.0 199.0 220.0
Pd2+—F− 9 206.8 11.6 0.0 192.4 194.5 211.0 216.8 500.0
Pd4+—F− 10 186.6 1.0 0.0 167.0 184.5 187.0 189.5 500.0
Ag+—F− 9 250.3 24.8 200.0 220.9 226.5 247.0 275.5 300.0
Ag2+—F− 12 205.5 4.8 180.0 195.2 204.0 206.4 207.6 240.0
Cd2+—F− 23 222.1 14.4 180.0 200.3 215.5 221.7 232.2 270.0
Y3+—Cl− 10 274.0 23.4 220.0 227.0 259.0 278.0 285.5 330.0
Zr3+—Cl− 9 250.6 6.8 0.0 232.9 250.8 252.3 253.8 500.0
Zr4+—Cl− 9 240.1 6.7 0.0 230.4 232.5 244.2 245.4 500.0
Nb—Cl− 9 245.4 11.2 0.0 228.9 238.5 243.0 258.5 500.0
Nb5+—Cl− 13 232.8 18.1 200.0 215.3 224.2 227.0 231.5 300.0
Mo2+—Cl− 11 240.8 6.2 0.0 227.1 238.5 240.5 244.5 500.0
Mo3+—Cl− 11 240.1 2.1 0.0 236.6 238.5 240.2 241.6 500.0
Mo4+—Cl− 3 224.3 5.8 0.0 220.1 220.8 221.5 230.5 500.0
Mo5+—Cl− 7 230.7 5.8 0.0 222.7 226.8 229.0 236.5 500.0
Mo6+—Cl− 12 229.3 4.7 210.0 221.2 225.3 230.0 233.3 260.0
Ru2+—Cl− 11 233.9 6.1 200.0 219.1 231.2 235.0 238.2 260.0
Ru3+—Cl− 15 234.7 5.4 220.0 230.4 231.9 233.4 235.5 270.0
Ru4+—Cl− 8 234.0 3.0 220.0 230.3 231.3 234.0 236.0 260.0
Rh3+—Cl− 9 232.3 2.8 210.0 228.4 230.2 231.7 234.8 260.0
Pd2+—Cl− 15 230.7 2.9 210.0 227.5 228.9 230.2 231.4 260.0
Pd4+—Cl− 3 210.3 16.3 0.0 198.3 199.5 203.0 228.5 500.0
Ag+—Cl− 16 261.9 13.5 0.0 237.6 250.0 262.0 271.0 500.0
Cd2+—Cl− 58 258.0 8.5 220.0 241.9 252.1 258.5 263.0 300.0
Zr3+—Br− 4 266.5 1.0 0.0 264.4 266.0 266.7 267.3 500.0
Nb5+—Br− 7 253.3 7.8 230.0 240.7 250.8 252.5 256.5 290.0
Mo—Br− 12 257.7 14.0 0.0 229.2 254.5 256.0 260.0 500.0
Rh—Br− 3 245.7 4.2 0.0 240.3 241.5 247.0 248.5 500.0
Ag—Br− 6 267.7 17.8 0.0 254.6 258.5 260.0 267.0 500.0
Cd2+—Br− 16 274.0 12.1 250.0 253.6 264.0 276.7 284.0 310.0
Zr—I− 21 287.1 1.7 250.0 284.0 286.2 287.1 288.0 320.0
Zr4+—I− 5 284.6 14.2 0.0 268.2 269.2 294.3 295.2 500.0
Nb—I− 13 277.3 16.3 0.0 241.3 265.2 281.5 283.8 500.0
Nb5+—I− 4 274.5 8.7 0.0 262.4 264.0 274.0 280.0 500.0
Mo—I− 4 270.0 12.7 0.0 250.4 252.0 276.0 277.0 500.0
Ru—I− 3 269.7 2.3 250.0 266.3 267.5 270.5 271.2 300.0
Ag+—I− 61 283.1 11.6 250.0 267.0 278.2 281.2 284.9 330.0
Cd2+—I− 30 293.5 11.0 260.0 273.0 291.0 297.6 299.1 340.0
La3+—F− 30 240.9 5.8 0.0 234.3 237.4 240.6 242.2 500.0
Hf4+—F− 9 209.9 10.4 0.0 198.4 202.2 205.0 217.2 500.0
Ta5+—F− 29 190.6 5.5 160.0 178.9 188.4 191.2 194.6 220.0
W6+—F− 13 183.5 11.8 150.0 163.3 177.2 179.2 192.8 230.0
Re—F− 18 187.6 14.9 150.0 163.8 179.0 182.0 195.0 240.0
Os—F− 10 182.8 14.9 0.0 157.0 171.0 184.0 194.5 500.0
Pt4+—F− 12 189.0 6.8 0.0 169.2 188.6 189.4 192.0 500.0
Au3+—F− 7 196.1 3.8 180.0 190.4 191.8 198.2 199.1 220.0
Hg—F− 19 278.1 26.8 0.0 215.9 271.8 282.3 287.5 500.0
Hg2+—F− 25 242.7 23.8 0.0 204.5 223.5 243.0 261.9 500.0
La3+—Cl− 21 293.1 16.1 0.0 256.0 294.2 297.0 302.4 500.0
Ta5+—Cl− 4 227.5 2.5 210.0 224.4 226.0 227.0 228.0 260.0
W—Cl− 9 234.1 6.5 210.0 224.9 228.5 233.0 240.5 260.0
W6+—Cl− 8 219.2 11.1 190.0 202.8 208.0 224.0 228.0 270.0
Re—Cl− 46 231.6 8.7 200.0 218.3 227.0 231.1 235.4 280.0
Os—Cl− 14 239.3 6.8 200.0 226.7 236.2 238.0 243.8 280.0
Ir—Cl− 11 235.4 7.4 200.0 223.1 230.8 234.5 240.5 270.0
Pt2+—Cl− 26 231.5 3.4 200.0 226.6 229.5 231.0 232.8 270.0
Pt4+—Cl− 31 231.9 7.0 0.0 225.1 230.2 232.1 234.2 500.0
Au+—Cl− 14 241.1 16.6 0.0 225.4 229.7 233.0 249.0 500.0
Au3+—Cl− 35 232.1 12.8 200.0 219.5 226.1 227.7 234.5 300.0
Hg+—Cl− 7 255.0 9.5 230.0 242.7 250.5 251.7 258.5 300.0
Hg2+—Cl− 68 250.5 25.5 200.0 223.4 231.0 238.0 276.7 310.0
La3+—Br− 3 310.3 34.1 0.0 270.3 271.5 329.0 330.5 500.0
W6+—Br− 5 245.0 10.7 0.0 230.5 242.5 244.5 245.8 500.0
Re3+—Br− 4 237.5 6.6 0.0 232.2 233.0 234.0 238.0 500.0
Os4+—Br− 3 246.3 6.4 0.0 238.3 239.5 249.0 250.5 500.0
Ir3+—Br− 4 244.0 3.8 0.0 240.2 241.0 242.0 246.0 500.0
Pt2+—Br− 9 246.3 6.6 0.0 240.9 242.8 244.5 246.8 500.0
Pt4+—Br− 8 242.5 10.6 200.0 216.8 243.0 246.0 248.0 270.0
Pt—Br 22 247.4 7.9 230.0 240.2 243.2 246.0 248.5 290.0
Au3+—Br− 10 243.0 2.7 0.0 239.0 241.0 242.7 245.0 500.0
Hg+—Br− 5 263.0 14.3 0.0 240.5 256.5 269.0 271.5 500.0
Hg2+—Br− 27 268.8 25.9 230.0 238.7 247.5 257.0 294.5 330.0
Os—I 8 275.8 4.8 0.0 272.2 273.0 274.0 276.0 500.0
Pt4+—I− 10 266.2 2.1 0.0 262.5 264.5 266.5 267.8 500.0
Pt—I 24 265.4 3.9 0.0 258.4 263.0 265.2 268.0 500.0
Au+—I− 4 258.5 3.0 0.0 254.4 256.0 258.0 261.0 500.0
Au3+—I− 3 265.0 3.5 0.0 262.1 262.8 263.5 268.5 500.0
Hg2+—I− 40 284.2 27.3 0.0 258.0 267.3 273.6 281.0 500.0