International
Tables for
Crystallography
Volume C
Mathematical, physical and chemical tables
Edited by E. Prince

International Tables for Crystallography (2006). Vol. C. ch. 1.4, p. 21

Section 1.4.2.1. Symmorphic space groups

A. J. C. Wilsona

a St John's College, Cambridge CB2 1TP, England

1.4.2.1. Symmorphic space groups

| top | pdf |

The 73 space groups known as `symmorphic' are in one-to-one correspondence with the arithmetic crystal classes, and their standard `short' symbols (Bertaut, 2005[link]) are obtained by interchanging the order of the geometric crystal class and the Bravais cell in the symbol for the arithmetic space group. In fact, conventional crystallographic symbolism did not distinguish between arithmetic crystal classes and symmorphic space groups until recently (de Wolff et al., 1985[link]); the symbol of the symmorphic group was used also for the arithmetic class.

This relationship between the symbols, and the equivalent rule-of-thumb symmorphic space groups are those whose standard (short) symbols do not contain glide planes or screw axes, reveal nothing fundamental about the nature of symmorphism; they are simply a consequence of the conventions governing the construction of symbols in International Tables for Crystallography.3

Although the standard symbols of the symmorphic space groups do not contain screw axes or glide planes, this is a result of the manner in which the space-group symbols have been devised. Most symmorphic space groups do in fact contain screw axes and/or glide planes. This is immediately obvious for the symmorphic space groups based on centred cells; C2 contains equal numbers of diad rotation axes and diad screw axes, and Cm contains equal numbers of reflection planes and glide planes. This is recognized in the `extended' space-group symbols (Bertaut, 2005[link]), but these are clumsy and not commonly used; those for C2 and Cm are [C1^{ 2}_{ 2_{1}}\!1] and [C1^{m}_{ a}1], respectively. In the more symmetric crystal systems, even symmorphic space groups with primitive cells contain screw axes and/or glide planes; [P422] ([P42^{ 2}_{2_{1}}]) contains many diad screw axes and P4/mmm ([P4/m2/m^{ 2/m}_{ 2_{1}/g}]) contains both screw axes and glide planes.

The balance of symmetry elements within the symmorphic space groups is discussed in more detail in Subsection 9.7.1.2[link] .

References

First citation Bertaut, E. F. (2005). Synoptic tables of space-group symbols. International tables for crystallography, Vol. A, edited by Th. Hahn, Part 4. Heidelberg: Springer.Google Scholar
First citation Wolff, P. M. de, Belov, N. V., Bertaut, E. F., Buerger, M. J., Donnay, J. D. H., Fischer, W., Hahn, Th., Koptsik, V. A., Mackay, A. L., Wondratschek, H., Wilson, A. J. C. & Abrahams, S. C. (1985). Nomenclature for crystal families, Bravais-lattice types and arithmetic classes. Acta Cryst. A41, 278–280.Google Scholar








































to end of page
to top of page