International Tables for Crystallography


Sample-thickness effects
Frank Bridges. International Tables for Crystallography (2024). Vol. I [ doi:10.1107/S1574870722003512 ]

Abstract

Uniformity of the samples used for X-ray absorption fine-structure (EXAFS) and X-ray absorption near-edge structure studies is critical for obtaining high-quality data. Defects in the sample, including pinholes, cracks, tapers and more irregular thickness variations, generally lead to a reduced amplitude of the EXAFS oscillations and distortion of the absorption edge. These effects become worse when there is significant background absorption from other atoms in the system. In addition, if the intensity of the X-ray beam is non-uniform across the sample this non-uniformity will couple with sample non-uniformity to produce unwanted structure as a function of energy, as happens at monochromator glitches.


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About International Tables for Crystallography

International Tables for Crystallography is the definitive resource and reference work for crystallography. The multi-volume series comprises articles and tables of data relevant to crystallographic research and to applications of crystallographic methods in all sciences concerned with the structure and properties of materials.