International Tables for Crystallography


Magnetic X-ray techniques
Gerrit van der Laan. International Tables for Crystallography (2024). Vol. I [ doi:10.1107/S157487072200163X ]

Abstract

The underlying theoretical aspects of X-ray spectroscopies are recapitulated with special emphasis on applications to magnetic systems. Prominence is placed on common conceptual aspects, while highlighting the differences in information that they may offer. X-ray scattering can be used to investigate the electronic and magnetic long-range order in crystals and ordered materials. The crystal symmetry of the sample and the X-ray polarization state have a profound effect on the scattering amplitude of X-ray resonant magnetic scattering (XRMS). Expressions for X-ray magnetic circular and linear dichroism (XMCD and XMLD, respectively) can be derived directly from those for XRMS. The photon–matter interaction for electric and magnetic multipole fields is presented from a general point of view, which reveals the physical implications of the various terms in the cross section for X-ray absorption. X-ray optical activity is due to mixed terms of different multipole rank of the electric and magnetic fields. The different optical effects, such as XMCD, X-ray natural circular dichroism (XNCD) and X-ray magnetic chiral dichroism (XMχD), can be distinguished by their properties under space inversion and time reversal.


Access, prices and ordering

International Tables for Crystallography is available online as a full set of volumes through Wiley.

set

If you have already registered and are using a computer listed in your registration details, please email [email protected] for assistance.

About International Tables for Crystallography

International Tables for Crystallography is the definitive resource and reference work for crystallography. The multi-volume series comprises articles and tables of data relevant to crystallographic research and to applications of crystallographic methods in all sciences concerned with the structure and properties of materials.