International Tables for Crystallography (2006). Vol. D. ch. 3.3, pp. 393-448
https://doi.org/10.1107/97809553602060000644 |
Chapter 3.3. Twinning of crystals
Contents
- 3.3. Twinning of crystals (pp. 393-448) | html | pdf | chapter contents |
- 3.3.1. Crystal aggregates and intergrowths (pp. 393-394) | html | pdf |
- 3.3.2. Basic concepts and definitions of twinning (pp. 394-398) | html | pdf |
- 3.3.3. Morphological classification, simple and multiple twinning (pp. 398-399) | html | pdf |
- 3.3.4. Composite symmetry and the twin law (pp. 399-402) | html | pdf |
- 3.3.5. Description of the twin law by black–white symmetry (pp. 402-403) | html | pdf |
- 3.3.6. Examples of twinned crystals (pp. 403-412) | html | pdf |
- 3.3.6.1. Inversion twins in orthorhombic crystals (p. 403) | html | pdf |
- 3.3.6.2. Twinning of gypsum (pp. 403-404) | html | pdf |
- 3.3.6.3. Twinning of low-temperature quartz (α-quartz) (pp. 404-405) | html | pdf |
- 3.3.6.4. Twinning of high-temperature quartz (β-quartz) (pp. 405-406) | html | pdf |
- 3.3.6.5. Twinning of rhombohedral crystals (p. 406) | html | pdf |
- 3.3.6.6. Spinel twins (pp. 407-408) | html | pdf |
- 3.3.6.7. Growth and transformation twins of K2SO4 (p. 408) | html | pdf |
- 3.3.6.8. Pentagonal–decagonal twins (p. 408) | html | pdf |
- 3.3.6.9. Multiple twins of rutile (pp. 408-409) | html | pdf |
- 3.3.6.10. Variety of twinning in gibbsite, Al(OH)3 (pp. 409-410) | html | pdf |
- 3.3.6.11. Plagioclase twins (p. 410) | html | pdf |
- 3.3.6.12. Staurolite (pp. 410-411) | html | pdf |
- 3.3.6.13. BaTiO3 transformation twins (pp. 411-412) | html | pdf |
- 3.3.6.14. Twins of twins (p. 412) | html | pdf |
- 3.3.7. Genetic classification of twins (pp. 412-416) | html | pdf |
- 3.3.8. Lattice aspects of twinning (pp. 416-422) | html | pdf |
- 3.3.8.1. Basic concepts of Friedel's lattice theory (p. 417) | html | pdf |
- 3.3.8.2. Lattice coincidences, twin lattice, twin lattice index (pp. 417-418) | html | pdf |
- 3.3.8.3. Twins with three-dimensional twin lattices (`triperiodic' twins) (pp. 418-419) | html | pdf |
- 3.3.8.4. Approximate (pseudo-)coincidences of two or more lattices (pp. 419-420) | html | pdf |
- 3.3.8.5. Twin obliquity and lattice pseudosymmetry (pp. 420-421) | html | pdf |
- 3.3.8.6. Twinning of isostructural crystals (p. 422) | html | pdf |
- 3.3.8.7. Conclusions (p. 422) | html | pdf |
- 3.3.9. Twinning by merohedry and pseudo-merohedry (pp. 422-425) | html | pdf |
- 3.3.9.1. Definitions of merohedry (pp. 422-423) | html | pdf |
- 3.3.9.2. Types of twins by merohedry and pseudo-merohedry (pp. 423-425) | html | pdf |
- 3.3.9.2.1. Merohedral twins of lattice index (p. 423) | html | pdf |
- 3.3.9.2.2. Pseudo-merohedral twins of lattice index (p. 423) | html | pdf |
- 3.3.9.2.3. Twinning with partial lattice coincidence (lattice index ) (pp. 423-424) | html | pdf |
- 3.3.9.2.4. Twinning with partial lattice pseudo-coincidence (lattice index ) (pp. 424-425) | html | pdf |
- 3.3.9.3. Pseudo-merohedry and ferroelasticity (p. 425) | html | pdf |
- 3.3.10. Twin boundaries (pp. 426-444) | html | pdf |
- 3.3.10.1. Contact relations in twinning (p. 426) | html | pdf |
- 3.3.10.2. Strain compatibility of interfaces (pp. 426-430) | html | pdf |
- 3.3.10.2.1. Sapriel approach to permissible (compatible) boundaries in ferroelastic (non-merohedral) transformation twins (pp. 427-428) | html | pdf |
- 3.3.10.2.2. Extension to non-merohedral growth and mechanical twins (pp. 428-429) | html | pdf |
- 3.3.10.2.3. Permissible boundaries in merohedral twins (lattice index ) (pp. 429-430) | html | pdf |
- 3.3.10.2.4. Permissible twin boundaries in twins with lattice index (p. 430) | html | pdf |
- 3.3.10.3. Electrical constraints of twin interfaces (pp. 430-432) | html | pdf |
- 3.3.10.4. Displacement and fault vectors of twin boundaries (pp. 432-434) | html | pdf |
- 3.3.10.5. Examples of structural models of twin boundaries (pp. 434-437) | html | pdf |
- 3.3.10.6. Observations of twin boundaries by transmission electron microscopy (pp. 437-439) | html | pdf |
- 3.3.10.6.1. Anatase, TiO2 (Penn & Banfield, 1998, 1999) (p. 437) | html | pdf |
- 3.3.10.6.2. SnO2 (rutile structure) (p. 437) | html | pdf |
- 3.3.10.6.3. (111) twin interface in BaTiO3 [cf. Section 3.3.8.3(iii)] (p. 437) | html | pdf |
- 3.3.10.6.4. bicrystal boundaries in Cu and Ag (pp. 437-438) | html | pdf |
- 3.3.10.6.5. Fivefold cyclic twins in nanocrystalline materials (pp. 438-439) | html | pdf |
- 3.3.10.7. Twin textures (pp. 439-442) | html | pdf |
- 3.3.10.7.1. Merohedral (non-ferroelastic) twins (see Sections 3.3.9 and 3.3.10.2.3) (p. 439) | html | pdf |
- 3.3.10.7.2. Non-merohedral (ferroelastic) twins (p. 439) | html | pdf |
- 3.3.10.7.3. Fitting problems of ferroelastic twins (pp. 440-441) | html | pdf |
- 3.3.10.7.4. Tweed microstructures (pp. 441-442) | html | pdf |
- 3.3.10.7.5. Twin textures in polycrystalline aggregates (p. 442) | html | pdf |
- 3.3.10.8. Twinning dislocations (pp. 442-443) | html | pdf |
- 3.3.10.9. Coherent and incoherent twin interfaces (pp. 443-444) | html | pdf |
- 3.3.11. Glossary (pp. 444-445) | html | pdf |
- References | html | pdf |
- Figures
- Fig. 3.3.1.1. Parallel intergrowth (a) of spinel octahedra and (b) of hexagonal quartz prisms (p. 393) | html | pdf |
- Fig. 3.3.1.2. (a) Optical anomaly of a cubic mixed (K,NH4)-alum crystal grown from aqueous solution, as revealed by polarized light between crossed polarizers (p. 393) | html | pdf |
- Fig. 3.3.2.1. Schematic illustration of the orientation relations of triclinic twin partners, see Section 3.3.2.3.1 (p. 395) | html | pdf |
- Fig. 3.3.2.2. As Fig. 3.3.2.1, (a) for twin element (iii) `rational twofold twin axis' and (b) for twin element (iv) `irrational twin mirror plane' (see text); common lattice row [uvw] for both cases (p. 395) | html | pdf |
- Fig. 3.3.2.3. Illustration of the Kantennormalengesetz (complex twin) for twin elements (v) and (vi) (see text); common lattice row [uvw] for both cases (p. 396) | html | pdf |
- Fig. 3.3.2.4. (a) Triple growth twin of orthorhombic aragonite, CaCO3, with pseudo-threefold twin axis (p. 397) | html | pdf |
- Fig. 3.3.3.1. Schematic illustration of simple (polysynthetic) and multiple (cyclic) twins (p. 398) | html | pdf |
- Fig. 3.3.4.1. Gypsum dovetail twin: schematic illustration of the coset of alternative twin operations (p. 399) | html | pdf |
- Fig. 3.3.4.2. Twinning of an orthorhombic crystal with equivalent twin mirror planes (110) and (p. 400) | html | pdf |
- Fig. 3.3.6.1. Dovetail twin (a) and Montmartre twin (b) of gypsum (p. 403) | html | pdf |
- Fig. 3.3.6.2. Distinction of the four different domain states generated by the three merohedral twin laws of low-quartz and of quartz homeotypes (p. 405) | html | pdf |
- Fig. 3.3.6.3. The four variants of Japanese twins of quartz (p. 406) | html | pdf |
- Fig. 3.3.6.4. Twin intergrowth of `obverse' and `reverse' rhombohedra of rhombohedral FeBO3 (p. 406) | html | pdf |
- Fig. 3.3.6.5. Contact growth twin of calcite with the same twin law as FeBO3 in Fig. 3.3.6.4 (p. 407) | html | pdf |
- Fig. 3.3.6.6. Spinel (111) twins of cubic crystals (two orientation states) (p. 407) | html | pdf |
- Fig. 3.3.6.7. Pseudo-hexagonal growth twin of K2SO4 showing six sector domains in three orientation states (p. 408) | html | pdf |
- Fig. 3.3.6.8. Pentagonal–decagonal twins (p. 408) | html | pdf |
- Fig. 3.3.6.9. Various forms of rutile (TiO2) twins, with one or several equivalent twin reflection planes {011} (p. 409) | html | pdf |
- Fig. 3.3.6.10. Sixfold reflection twin of gibbsite, Al(OH)3, with equivalent (110) and ), both as twin mirror and composition planes (p. 410) | html | pdf |
- Fig. 3.3.6.11. Polysynthetic albite twin aggregate of triclinic feldspar, twin reflection and composition plane (010) (p. 410) | html | pdf |
- Fig. 3.3.6.12. Pericline twin of triclinic feldspar (p. 411) | html | pdf |
- Fig. 3.3.6.13. Twinning of staurolite (p. 411) | html | pdf |
- Fig. 3.3.7.1. Orthoclase (monoclinic K-feldspar) (p. 413) | html | pdf |
- Fig. 3.3.7.2. Photographs of (001) plates ( 20 mm diameter, 1 mm thick) of NH4LiSO4 between crossed polarizers (p. 413) | html | pdf |
- Fig. 3.3.7.3. Mechanical twins of calcite, CaCO3 (p. 415) | html | pdf |
- Fig. 3.3.8.1. Lattice relations of twins of tetragonal crystals with primitive lattice (p. 419) | html | pdf |
- Fig. 3.3.8.2. (a) A (110) silicon slice (10 cm diameter, 0.3 mm thick), cut from a Czochralski-grown tricrystal for solar-cell applications (p. 419) | html | pdf |
- Fig. 3.3.10.1. (a) Classical description of mechanical twinning by homogeneous shear deformation (p. 427) | html | pdf |
- Fig. 3.3.10.2. Boundaries B–B between 180° domains (merohedral twins) of pyroelectric crystals (p. 431) | html | pdf |
- Fig. 3.3.10.3. Charged and uncharged boundaries B–B of non-merohedral twins of pseudo-hexagonal NH4LiSO4 (p. 432) | html | pdf |
- Fig. 3.3.10.4. Lattice representation of twin displacement vectors (p. 432) | html | pdf |
- Fig. 3.3.10.5. HRTEM micrograph of anatase, TiO2, with a (112) reflection twin boundary (arrows), viewed edge-on along (p. 433) | html | pdf |
- Fig. 3.3.10.6. Structural model of the (110) twin boundary of aragonite (after Bragg, 1924), projected along the pseudo-hexagonal c axis (p. 435) | html | pdf |
- Fig. 3.3.10.7. Simplified structural model of a Dauphiné twin boundary in quartz (p. 435) | html | pdf |
- Fig. 3.3.10.8. KLiSO4: Bulk tetrahedral framework structures and models of (0001) twin boundary structures of phases III and IV (p. 436) | html | pdf |
- Fig. 3.3.10.9. (a) HRTEM micrograph of a coherent (111) twin boundary in BaTiO3, projected along (p. 438) | html | pdf |
- Fig. 3.3.10.10. (a) Schematic block diagram of a bicrystal (spinel twin) for (p. 438) | html | pdf |
- Fig. 3.3.10.11. HRTEM micrograph of a fivefold-twinned Ge nanocrystal (right) in an amorphous Ge film formed by vapour deposition on an NaCl cleavage plane (p. 439) | html | pdf |
- Fig. 3.3.10.12. Illustration of space-filling problems of domains for a (ferroelastic) orthorhombic monoclinic phase transition with an angle (exaggerated) of spontaneous shear (p. 440) | html | pdf |
- Fig. 3.3.10.13. Thin section of tetragonal leucite, K(AlSi2O6), between crossed polarizers (p. 441) | html | pdf |
- Fig. 3.3.10.14. Twin textures generated by the two different hexagonal-to-orthorhombic phase transitions of KLiSO4 (p. 441) | html | pdf |
- Fig. 3.3.10.15. Definition of the Burgers vector b of a twinning dislocation TD (p. 443) | html | pdf |
- Tables
- Table 3.3.4.1. Gypsum, dovetail twins: coset of alternative twin operations (twin law), given in orthorhombic axes of the composite symmetry (p. 400) | html | pdf |
- Table 3.3.4.2. Reduced composite symmetries and for the orthorhombic example in Fig. 3.3.4.2 (p. 401) | html | pdf |
- Table 3.3.6.1. Orthorhombic inversion twins: coset of alternative twin operations (twin law) (p. 403) | html | pdf |
- Table 3.3.6.2. Gypsum: cosets of alternative twin operations of the dovetail and the Montmartre twins, referred to their specific orthorhombic axes (subscripts D and M) (p. 404) | html | pdf |
- Table 3.3.6.3. Dauphiné twins of α-quartz: coset of alternative twin operations (twin law) (p. 404) | html | pdf |
- Table 3.3.6.4. The four different variants of Japanese twins according to Frondel (1962) (p. 405) | html | pdf |
- Table 3.3.6.5. Plagioclase: albite and pericline twins (p. 410) | html | pdf |
- Table 3.3.8.1. Lattice planes (hkl) and lattice rows [uvw] that are mutually perpendicular (after Koch, 2004) (p. 418) | html | pdf |
- Table 3.3.8.2. Examples of calculated obliquities and lattice indices [j] for selected (hkl)[uvw] combinations and their relation to twinning (p. 421) | html | pdf |
- Table 3.3.9.1. Staurolite, 60° and 90° twins (p. 425) | html | pdf |
- Table 3.3.10.1. Examples of permissible twin boundaries for higher-order merohedral twins ([j]> 1) (p. 430) | html | pdf |